Definitely .707!
But...do you know why .707 is what it is?
There is mathematical perfection behind this alignment, which is why I prefer it over all others. .707 is the Golden Ratio. You can read about this stuff from other places later if that interests you, but to me it has great significance. Did you know that the entire universe and all of the things (large and small) relate to this ratio? The Phi spiral that makes up the galaxy is a mere example of how this ratio plays out. I think I could show you about 1000 examples given time to think deeply about it all. The octave is another example of it.
Because of the "perfect" alignment, I choose to get as close as possible to exactly .707 on most of my sealed box builds. Granted, I could easily be off by as much as 10% due to spec inaccuracy, temp differences, etc., but to me and my mild OCD, .707 or at least the attempt to get there does it for me.
Don't forget that the most important reasons to go for .707 are to achieve the most area under the curve of response, as well as to avoid sub "ringing" or overdamping / underdamping. I'm very certain that if you put a sub in 3 different boxes, one "perfect", one too large, and one too small, and tested them out in a listening room, you'd likely find the "perfect" alignment to be the most musical and more importantly, the most natural.